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Q.

Given reagents are HCl, NaOH, ZnCl2, Na2CO3, NH4Cl and Zn. Which of these reagent(s) can intensify hydrolysis of FeCl3 when added to its solution

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a

NaOH, Na2CO3

b

NaOH, NH4Cl, HCl

c

NH4Cl, HCl, ZnCl2

d

Na2CO3, NaOH + HCl

answer is A.

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Detailed Solution

The hydrolysis of FeCl3 can be intensified by adding a strong base or a weak acid.

Out of the given reagents, option (a) NaOH and Na2CO3 both are bases and can intensify hydrolysis of FeCl3.

Option (b) NH4Cl and HCl are both acids, and HCl is a strong acid that can compete with the hydrolysis of FeCl3. Therefore, option (b) cannot intensify the hydrolysis of FeCl3.

Option (c) Na2CO3 is a base that can intensify the hydrolysis of FeCl3, but adding NaOH and HCl together may neutralize each other's effects and not increase the hydrolysis of FeCl3. Therefore, option (c) may or may not intensify the hydrolysis of FeCl3.

Option (d) NH4Cl is an acid that cannot intensify the hydrolysis of FeCl3, while HCl and ZnCl2 are both strong acids that can compete with the hydrolysis of FeCl3. Therefore, option (d) cannot intensify the hydrolysis of FeCl3.

Therefore, the correct answer is option (a) NaOH and Na2CO3.

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Given reagents are HCl, NaOH, ZnCl2, Na2CO3, NH4Cl and Zn. Which of these reagent(s) can intensify hydrolysis of FeCl3 when added to its solution