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Q.

Given that:  
(i)  ΔfH of N2O is 82kJmol1

(ii) Bond energies of NN,N=N,O=O and N=O are 

 946, 418, 498 and 607 kJ mol-1 respectively, The resonance energy of N2O is :

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a

-66kJ 

b

-44kJ 

c

-62kJ 

d

-88kJ 

answer is A.

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Detailed Solution

N2(g)+12O2N2O(g)
NN(g)+12(O=O)N=N=O(g)
ΔHfo = [Energy required for breaking of bonds] —[Energy released for forming of bonds] 

          = [Enthalpies of reactants]-[Enthalpies of products]  
          =ΔHNN+12ΔHU=OΔHN=N+ΔHN=O =946+12×498(418+607)=170kJmol1 
Resonance energy = 170-82 = 88kJ mol-1

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