Q.

Given that interionic distance in Na+F crystal is 2.31A° and rF=1.36A°, which of the following predictions will be right? 

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a

rNa+rF=0.7

b

Effective nuclear charge for Na+ and F- are equal

c

Na+F will have rock salt type crystal structure

d

Coordination number of Na+= coordination number  of F-=6

answer is A, B, C.

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Detailed Solution

Na+& F are isoelectronic hence they will have same screening const (s) but not the effective nuclear charge,

RNa+/rF0.7 (coordination = 6, rock structure).

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Given that interionic distance in Na+F− crystal is 2.31A° and rF=1.36A°, which of the following predictions will be right?