Q.

Given that standard reduction potential of  
 Ni2+|Ni=0.25V   ;  Cu2+|Cu=0.34V
  Ag2+|Ag=0.80V ;  Zn2+|Zn=0.76V
Which of the following reactions under standard condition will not take place in the specific direction? 

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a

Ni(aq.)2++Cu(s) Ni(s)+Cu(aq.)2+

b

2Ag(aq.)++Cu(s) 2Ag(s)+Cu(aq.)2+

c

2H(aq.)++Zn(s) 3H2(g)+Zn(aq.)2+

d

2H(aq.)++Cu(s) H2(g)+Cu(aq.)2+

answer is A, C.

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