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Q.

Given that

2C(s)+2O2(g)CO2(g);ΔH=-787kJ ............. (i) H2(s)+12O2(g)H2O(l);ΔH=-286 kJ ..............(ii) C2H2(s)+52O2(g)2CO2(g)+2H2O(l);ΔH=-1301kJ.(iii)

Heat of formation of acetylene is

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a

-1802 KJ

b

+1802 KJ

c

-800 KJ

d

+228 KJ

answer is D.

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Detailed Solution

2C(s)+H2(g)C2H2(g) 

 The heat of formation of this reaction can be calculated as:

Eq. (i) + eq. (ii) – eq. (iii)

Therefore, ΔH=+228 kJ.

Therefore, the correct option is D.

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