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Q.

Given that 2NO2N2O4    ΔH= negative

The conditions at which the conversion of NO2 to N2O4 becomes more and more are

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a

lower temperature and higher pressure

b

higher temperature and lower pressure

c

lower temperature and lower pressure

d

higher temperature and higher pressure

answer is B.

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Detailed Solution

H negative means exothermic. Hence, lower temperature and higher pressure (aasAyg=-1) favours the formation of dimer.

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