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Q.

Given the data at 250C  
Ag+IAgI+e;E0=0.152VAgAg++e;E0=0.800V
What is the value of log Ksp for AgI? (2.303 RT /F = 0.059 V) 

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a

–16.13

b

–8.12

c

+8.612

d

–37.83

answer is A.

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Detailed Solution

 

Ag +I-AgI+e- Eo= 0.152V Ag Ag++e-         Eo= -0.8 V Ag+ +e-Ag        Eo  = 0.8V Ag+ +I- AgI+e- E o= 0.152V Ag++I-AgI              Eo= 0.952 V

Go=-nFE Go=+RT ln Ksp   -1 ×96500×0.952=8.314 × 298×2.303×log Ksp log Ksp= -16.1

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