Q.

Given the following molar conductivities at 250 C; HCl, 426Ω1cm2mol1; NaCl,126Ω1cm2mol1; NaC (sodium crotonate) 83Ω1cm2mol1, x×105 is the ionization constant of crotonic acid, if the conductivity of a 0.001 M crotonic acid solution is 3.83×105Ω1cm1. x =

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answer is 1.1.

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Detailed Solution

0M(HC)=0NaC+0HCl0NaCl0M=(83+426126)=383M=K×1000M=3.83×105×103103=3.83α=M0M=38.3383=0.1Ka=21α=0.001×(0.1)210.1=1.11×105

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