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Q.

Given the following molar conductivities at 25°C; HCl, 426Ω1cm2mol1; NaCl, 126 Ω1cm2mol1; NaC (sodium crotonate), 83Ω1cm2mol1, x × 10–5 is the ionization constant of crotonic acid, if the conductivity of a 0.001 M crotonic acid solution is 3.83 x10-5 Ω1cm1x=

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Detailed Solution

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=NaC+HClNaCl=83+426126=383M=3.83×105×1000/0.001=38.3α==38.3383=0.1=101Ka=C21α=103×101210.1=103×10120.9=1.11×105

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Given the following molar conductivities at 25°C; HCl, 426Ω−1cm2mol−1; NaCl, 126 Ω−1cm2mol−1; NaC (sodium crotonate), 83Ω−1cm2mol−1, x × 10–5 is the ionization constant of crotonic acid, if the conductivity of a 0.001 M crotonic acid solution is 3.83 x10-5 Ω−1cm−1⋅x=