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Q.

Given the hypothetical reaction  mechanism 
AStep-IBStep-IICStep-IIIDStep-IVE
and the data as:
The rate determining step is:
 

Species formedRate of its formation
B0.002 mole/h per mole of A
C0.030 mole/h per mole of B
D0.011 mole/h per mole of C
E0.0420 mole/h per mole of D

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a

Step I                     

b

Step II      

c

Step IV 

d

Step III                    

answer is A.

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Detailed Solution

The reaction taking place very slowly is  called rate determining step.

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