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Q.

Given two mixtures
I)  NaOH+Na2CO3
II)  NaHCO3+Na2CO3
100 ml of mixture I required ‘W’ and ‘X’ ml of 1 M HCl in separate titrations using phenolphthalein and Methyl orange indicators. While 100 ml of mixture II required ‘Y’ and ‘Z’ ml of same HCl solution in separate titration using same indicators.

 Column I (Substance) Column II (Molarity in solution)
ANa2CO3  in mixture IP(2wx)×102
BNa2CO3  in mixture IIQ(z2y)×102
CNaOH in mixture IRy×102
DNaHCO3  in mixture IIS(xw)×102

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a

A-S; B-R; C-Q; D-P

b

A-S; B-R; C-P; D-Q

c

A-P; B-Q; C-S; D-R 

d

A-P; B-S; C-Q; D-R

answer is B.

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