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Q.

GivenECr+3/Cr0=0.72V;EFe2+/Fe0=0.42 V
The potential for the cell, CrCr3+(0.1M)Fe2+(0.01M)Fe is 

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a

– 0.339 V

b

– 0.26 V

c

0.26 V

d

0.339 V

answer is C.

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Detailed Solution

Ecell o=Ecathode oEanode oEcell o=(0.42)(0.72)=+0.30V
For the given galvanic cell the reaction is written as
2Cr+3Fe(0.01M)2+2Cr(0.1M)3++3Fe
The reaction  Quitient (Qc) =Cr3+2Fe2+3=[0.1]2[0.01]3=104
The Nersnt equation is written as Ecell =Ecell o-0.0591n
logQccell=0.300.05916log104 on solving Ecell =+0.261V

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