Q.

Given ECr3+/Cro=0.72V,EFe2+/Feo=0.42V. The potential for the cell 

Cr  Cr+30.1MFe+20.01M  Fe is

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a

-0.399 V

b

0.26 V

c

0.339 V

d

-0.26 V

answer is A.

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Detailed Solution

As ECr3+/Cro=0.7V and EFe2+/Feo=0.42V

2Cr+3Fe2+3Fe+2Cr3+Ecell=Ecello0.05916log[Cr3+]2[Fe2+]3=(0.42+0.72)0.05916log[0.1]2[0.01]3=0.300.05916log[0.1]2[0.01]3=0.300.05916log104Ecell=0.2606V

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Given ECr3+/Cro=−0.72 V, EFe2+/Feo=−0.42 V. The potential for the cell Cr  Cr+30.1M∥Fe+20.01M  Fe is