Q.

GlucoseConc.HNO3X;    Glucose  Ag(NH3)2+Y;   X and Y respectively ar

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a

HOOCCH24CHO,    HOOCCH24COOH

b

HOOCCHOH4CHO,    HOOCCHOH4CH2OH

c

HOOCCHOH4COOH,    HOOCCHOH4CH2OH

d

HOOCCH24COOH,    HOOCCH24CH2OH

answer is C.

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Detailed Solution

 

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OHC -CHOH4-CH2OH Tollen reagentHOOC-CHOH4-CH2OH

Conc. nitric acid oxidizes both aldehyde group and primary alcohol  group to carboxylic acid.

Tollens reagent is a mild oxidant, it oxidizes only aldehyde group to carboxylic acid

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Glucose →Conc.HNO3X;    Glucose  →Ag(NH3)2+Y;   X and Y respectively ar