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Q.

Gold (molar mass =197.0gmol1 has a face-centred cubic unit cell. If its density is 19.7gcm3, the atomic radius of gold will be about 

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a

110.2 pm

b

121.4 pm

c

143.2 pm

d

154.0 pm

answer is C.

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Detailed Solution

Since ρ=NM/NA/a3=NM/NA/(22r)3, We have

    r=122NM/NAρ1/3=1224197.0gmol1/6.022×1023mol119.7gcm31/3=1224.05×108cm=1.432×108cm=143.2pm

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Gold (molar mass =197.0gmol−1 has a face-centred cubic unit cell. If its density is 19.7gcm−3, the atomic radius of gold will be about