Q.

 Group attached to
Benzene ring
 Electronic effect
exhibited
A)-OI)+I, +R
B)–CNII)–I, +M
C)-OCH3III)–I, -M
D)–CH3IV)+I, +M

Correct match is

 IIIIIIIV
1.CDBA
2.DCBA
3.CADB
4.DBCA

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a

2

b

1

c

3

d

4

answer is B.

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Detailed Solution

Groups in which the atom directly attached benzene ring have negative charge or lone pair show +M effect. 
Groups in which the atom directly attached benzene ring has multiple bond show –M effect and also –I effect.
-CH3 group shows +I and +R (hyper conjugation) effects.

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