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Q.

 group which deactivates the benzene ring  towards electrophilic substitution but which directs the incoming group principally to the O-Positions is 

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a

NH2

b

-CI

c

NO2

d

C2H5

answer is B.

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Detailed Solution

-Cl group is o-, p-directing due to +R effect ; however it is deactivating due to strong —I effect of Cl (difference from other o-, p-directing groups which are activating). The net result is that chlorobenzene undergoes o-, p-substitution, but with difficulty 

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