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Q.

ΔG us T plot in Ellingham diagram slopes downward for the reaction :

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a

Mg+12O2MgO

b

2Ag+12O2Ag2O

c

C+12O2CO

d

CO+12O2CO2

answer is C.

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Detailed Solution

ΔG us T plot in the Ellingham diagram slopes downward for the reaction as follows, C+12O2CO

Since the gas is used up during the reaction, the entropy decreases, which causes the term TS to have a positive value. Therefore, for the majority of the reduction reaction, slope S is positive.

For C+12O2CO, the oxidation process of carbon to carbon monoxide has a downward slope because the oxygen gas is consumed while the product created is also a gas, increasing the number of gaseous species and entropy.

Hence the correct option is C

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