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Q.

H2A is a weak diprotic acid. If the pH of 0.1M H2A solution is 3 and concentration of A2-  is 10-12 at 298K. select correct statement(s)

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a

The value of Ka1 is nearly 10-5

b

Concentration of OH- in solution is 10-3 M

c

H+total H+ from first step of ionization of acid H2A

d

PKa2PKa1=9

answer is A, B.

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Detailed Solution

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pH=12pKa1logC3=12PKq1+1;pKa1=5Ka1=105H2AH+HA
Option-a-Correct
At  Eq: cx x+yx xyx
y is very less. So x+yx&xyx
Ka1=x2cxHAH+A

At  eq: xyx y y
Ka2=y=1012;PKa2=12H+total =H+from H2A+H+from HA=x+yx
Option – b - Correct
From (c)PH=3H+=103M         Incorrect
From (d)PKa2PKa1=125=7           Incorrect

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