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Q.

H2A is a weak diprotic acid. If the pH of 0.1 M H2A solution is 3 and concentration of A2- is 10-12 at 25°C. Select correct statement(s)

 

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a

H+Total H+from first step of ionization of acid H2A

b

 Concentration of -OH in solution is 103M

c

 The value of Ka1 is nearly 105

d

pKa2pK1=9

answer is A, C.

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Detailed Solution

H2AH++HAy is very less so x+yxKa1=x2cx

At equilibrium 

 C- X x+y xy Ka2=y=1012;pKa2=12

HA1H++A2 at equilibrium  xy x+y ypKa2pKa1=125=7pH=12pKa1logC3=12pKa1+1pKa1=5

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