$H_{2} O_{2}$ is non-linear and non-planar molecule. Dihedral angle in gaseous phase is A ; and in crystalline from is B. Give the relation between A and B.

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A > B

A < B

A = B

None of these

answer is A.

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Detailed Solution

Dihedral angle of $H_{2} O_{2}$ in gaseous phase is $111^{0} . 30^{1}$ in crystalline form is $90^{0} . 15^{1}$ . So the angle increases solid to gaseous phase.

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