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Q.

H2O2 restores the colour of old lead painting , blackened by the action of H2S gas, by:

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a

converting PbO2 to Pb

b

oxidising PbS to PbSO4

c

converting.PbCO3 to Pb

d

oxidising PbSO3 to PbSO4

answer is B.

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Detailed Solution

Lead is present as Pb2+ and when H2S comes in contact with Pb2+, it forms PbS (black). This PbS is responsible for the blackening of the painting. To remove this blackness, paintings wash with H2O2, where H2O2 converts PbS (black) into PbSO4 (white). This helps in restoring the color of the old paintings.

PbSBlack+4H2O2PbSO4White+4H2O

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