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Q.

H2O2 acts as both oxidising and reducing agent. As oxidising agent, its product is H2O

but as reducing agent, its product is O2. Volume strength has great significance for chemical reactions. The strength of ‘10V’ means 1 volume (or liter) of H2O2 on decomposition (H2O2   H2O+12O2) gives 10 volumes (or liter) of oxygen at NTP.

15 g Ba(MnO4)2 sample containing inert impurity is completely reacting with 100 mL of ‘11.2 V’ H2O2, then what will be the % purity of Ba(MnO4)2 in the sample : (Atomic mass : Ba = 137, Mn = 55)

 

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a

10%

b

none of these

c

50%

d

5%

answer is C.

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Detailed Solution

Ba(MnO4)2+5H2O2+3H2SO4BaSO4+2MnSO4+5O2+8H2O
milliequivalents of Ba(MnO4)2 reacted = milliequivalents of H2O2 reacted

mE×1000=NV(ml)      ; EBa(MnO4)2  =37510  ; NH2O2 =vol.strength5.6 m375×  10×  1000=11.25.6×100   m=7.5  g    wt.  of  BaMnO42  in  sample  =  7.5  g%  purity  of  BaMnO42  in  sample  =7.515  ×  100=50%

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