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Q.

H2O2 dissociates into  H2O(l) and O2(g). All the H2O2 present in 1 L of 3.36 volume H2O2 is allowed to dissociate completely and all the released O2 is used for the combustion of 1.56 g of diborane  B2H6. If heat of combustion of B2H6 is -1900 kJ/mol, then heat released by combustion of 1.56 g of diborane with O2 produced by above H2O2 solution is –P kJ. Find value of P/95 . Given 1 mole of a gas occupies 22.4 L at STP.

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Detailed Solution

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B2H6+3O2B2O3+3H2O mol of B2H6=0.06
Mol of O2  required =0.06×3=0.18mol
So O2 is limiting reagent so only 0.05 mol of used for combustion
ΔHI=0.05×1900=95kJ

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