Q.

H2S  is a dibasic weak acid with dissociation constant  Ka1=107 and  Ka2=1014. The concentration of different chemical species produced by  H2S depends upon the pH  of  the solution in which it is present. Which of the following statement are correct

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a

If pH of solution is 12 then  HS concentration will be more than  H2S and  S2

b

If pH of solution is 6 then H2S  concentration is more than HS  and  S2

c

If pH of solution is 13 then  S2 concentration will be more than HS  and  .H2S

d

If pH of solution is 2 then  H2S concentration is more than  HS and  S2

answer is A, B, C.

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Detailed Solution

a)  107=102[HS][H2S][HS][H2S]=105
1021=104[S2][H2S][S2][H2S]=1017
b)  107=106[HS][H2S][HS][H2S]=107
1021=1012[S2][H2S][S2][H2S]=109
C)  107=1012[HS][H2S][HS][H2S]=105
 

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H2S  is a dibasic weak acid with dissociation constant  Ka1=10−7 and  Ka2=10−14. The concentration of different chemical species produced by  H2S depends upon the pH  of  the solution in which it is present. Which of the following statement are correct