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Q.

H2S2O8+2H2O2H2SO4+X which of the following statement is incorrect for X?

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a

It is used in detection of Ti4+

b

Dihedral angle: gas phase < solid phase

c

It acts as an oxidising as well as reducing agent in both acidic and alkaline medium.

d

In basic medium it changes Fe3+ to Fe2+

answer is A.

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Detailed Solution

When Peroxydisulfuric acid is treated with water,

H2S2O8+2H2O2H2SO4+H2O2

So,

 'X is H2O2

The dihedral angle in H2O2 in the gaseous phase is 111.5°.and in the solid phase is  90.2° .

Dihedral angle: gas phase > solid phase.

Thus, the statement given in option A is incorrect.

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