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Q.

H2S in the presence of HCl precipitates II group but not IV group because :

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a

HCl decreases concentration of S2

b

HCl increases concentration of Cl

c

HCl activates H2S

d

HCl lowers the solubility of H2S in solution

answer is C.

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Detailed Solution

H2S in the presence of HCl precipitates II group but not IV group because HCl decreases the concentration of S2.

The presence of HCl inhibitsH2S dissociation due to the common ion effect. The presence of H+ ion in HCl is a common ion to  H2S .Because of the decreased degree of dissociation of H2S,  the concentration of  S2 ion generated is minimal.

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