Q.

Half-life period of a first order reaction is 10 min. What percentage of the reaction will be completed in 100 min?

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a

75%

b

99.9%

c

25%

d

50%

answer is C.

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Detailed Solution

t1/2=10min R= ? K=0.693t1/2=0.69310k=2.303tlogRoR0.69310=2.303100logRoR0xlogR0R0x=0.693×102.303logR0R0x=3.00 Say R0x=RlogR0R=3R0=103R          ....(1)

Now, % of reactant left after 100 min=RR0×100

=R103R×100( from (1))=0.1%

% of reaction completed

=1000.1=99.9%

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