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Q.

Halogenation of which one of the following will yield m-substituted product with respect to methyl group as a major product?

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a

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b

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c

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d

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answer is C.

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Detailed Solution

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Electrophile will attack at ortho and para position with respect to better electron releasing group (ERG)

ERG : -OH>-CH3

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Para position with respect to -OH (+R) group and it will be meta position with respect to -CH3 group.

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