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Q.

HCCHExcess NaA Excess CH3ClB

The final product B of the above conversion 

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a

2-Butyne 

b

1-Butyne 

c

Propyne 

d

Monosodium acetylide

answer is A.

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Detailed Solution

Acetylene when treated with excess Na, leads to formation of sodium acetylide.

HCCH  Excess NaNa-CC-Na

This sodium acetylide on further reaction with excess CH3Cl gives 2- Butyne.

Na-CC-Na  Excess CH3ClCH3-CC-CH3

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