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Q.

HCHO with conc. alkali forms two compounds. The change in oxidation number would be 

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a

(0 to –2) in both the compounds 

b

(0 to + 2) in one compound and (0 to -2) in the second compound 

c

(0 to +2) in both the compounds

d

all the above are correct

answer is C.

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Detailed Solution

Oxidation number of any species change when they either gain or loose their fixed number of electrons in the stable compounds. When HCHO & NaOH react, it is called disproportionation reaction in which one compound is alcohol and other on hydrolysis gives carboxylic acid. 

Formaldehyde has no alpha-hydrogen atom when reacts with NaOH it is called Cannizzaro’s reaction. 

 2HC0HO+NaOHHC+2OONa+C-2H3OH 

Hence, the correct answer is option (C) (0 to + 2) in one compound and (0 to -2) in the second compound.

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