Q.

 HClO3+HClX(yellowgas)+A(greenishyellow  gas)+H2O
Select the correct statement(s) with respect to X and A ?
(Given that X is an oxide of chlorine)

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a

Both are used for purifying drinking water

b

Gas ‘A’ liberates the reddish brown gas from an aqueous solution of bromide

c

'X’ is paramagnetic where as ‘A’ is diamagnetic

d

Both undergo disproportionation reactions when dissolves in alkali

answer is A, B, C, D.

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Detailed Solution

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X =  ClO2 and  A=Cl2
Cl2+BrBr2+Cl
Cl2+NaOHNaCl+NaOCl(NaClO3)+H2O
ClO2+NaOHNaClO2+NaClO3+H2O
 

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