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Q.

HCl was passed through a solution of  CaCl2 , MgCl2and NaCl. Which of the following compound(s) crystallise(s) ?

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a

only NaCl

b

Only MgCl2

c

NaCl, MgCl2 and  CaCl2

d

Both MgCl2 and  CaCl2

answer is A.

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Detailed Solution

Solubility of NaCl is less than  CaCl2 and MgCl2.On passing HCl through the saturated solution of NaCl containing CaCl2 and MgCl2 , NaCl only precipitates, because its Ionic product (KIP) exceeds solubility product most easily.

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