Q.

Heat of formation of –

 MX(ΔH)=-550kJmol-1           

 Heat of sublimation of metal (M)

 = + 80 kJ mol-1

Heat of dissociation of X2 

= 155 kJ mol-1 

 Ionisation energy of M = 374 kJ mol-1

 Electron gain enthalpy of X = -343 kJ mol-1

The lattice enthalpy (in kJ mol-1) of the salt MX(s) from the above data is 

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a

402

b

-816

c

-324.5

d

-738.5

answer is A.

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Detailed Solution

U=S+I+D2-E=Q

=80+374+1552-343-550=-738.5

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