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Q.

Heat of neutralization of H2SO4 with NaOH is -xKJ. Then the heat of ionisation of water is

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a

<xKJ

b

-xKJ

c

>xKJ

d

xKJ

answer is B.

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Detailed Solution

Chemical reaction

H2SO42H++SO42-

2H++2OH-2H2O;  ΔH-=-x kJ2

Ionization of Water is the reverse of heat of neutralization \  the value of heat will be equal but in reverse Sign.

The expression of ionization of Water

2H2O2H++2OH-;  ΔH=+x kJ

Hence the correct answer is (B) xKJ.

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Heat of neutralization of H2SO4 with NaOH is -xKJ. Then the heat of ionisation of water is