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Q.

Heat Q=32RT is supplied to 4 moles of an ideal diatomic gas kept in closed container at temperature T . how many moles of the gas are disassociated into atoms if temperature of gas is constant?

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answer is 3.

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Detailed Solution

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Let x mole of the gas be dissociated, x moles of atomic becomes 2x moles of a  monatomic  gas after dissociation.
Internal energy of n moles of an ideal gas =  32nRT for monatomic gas 

and U = 52nRT  for  diatomic gas 

so, (internal energy of 2x moles of monoatomic gas + internal energy of (4 –x) moles of a diatomic gas) – internal energy of 4 moles of a diatomic gas = 32nRT(given)

 (2x)(3RT2)+(4x)(5RT2)(4)(5RT2)=32RT  

on solving x = 3 moles

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