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Q.

Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H atom is suitable for this ?
Given: Rydberg constant RH=105cm1,h=6.6×1034Js,c=3×108m/s

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a

Lyman series, ∞→1

b

Paschen series, 5→3

c

Balmer series, ∞→2

d

Paschen series, ∞→3

answer is A.

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Detailed Solution

λ=900nm                 H-atom (Z=1)=9×105cmRH=105cm1 Ryderg eq. =1λ=RHZ2×1n121n221λ×RH=1n121n2219×105cm×105cm1=1n121n221n121n22=19

It is possible when n1 = 3, n2 =∞
Possible series : ∞→3

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