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Q.

Heat Q=32RT, is supplied to 4 moles of an ideal diatomic gas at temperature T, which remains constant. How many moles of the gas are dissolved into atoms?

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answer is 3.

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Detailed Solution

Let x moles of diatomic gas become 2x moles of a monoatomic gas after dissociation. Internal energy of n moles of an ideal gas :

Umono=32nRT      for monoatomic gas Udiatomic=52nRT       for diatomic gas 

So, (Internal energy of 2x moles of a monoatomic gas + internal energy of (4 - x) moles of a diatomic gas) - internal energy of 4 moles of a diatomic gas

=32RT (given) (2x)3RT2+(4x)52RT(4)52RT=32RT

On solving, x = 3 moles.

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