Q.

Henry’s constant (in kbar) for four gases α,β,γ and δ and  in water at 298 K is given below

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(density of water = 103kgm–3 at 298 K)
This table implies that :

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a

The pressure of a 55.5 molal solution of δ is 250 bar

b

α has the highest solubility in water at a given pressure

c

Solubility of γ at 308 K is lower than at 298 K

d

The pressure of a 55.5 molal solution of γ is 1 bar

answer is A.

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Detailed Solution

Given, Henry's constant
We need to find This table implies that, from the given option.

1. Pγ=KHXY Pγ=2×10-15×55.555.5+100018=2×10-5 K bar =2×10-2 bar   (2) Pδ=KHXδ Pδ=0.5×55.555.5+100018=.249 Kbar=249bar (3) As temperature rises, gases become less soluble.  (4) KH solubility  and lowest KH is for γ

Therefore, the correct option is A The pressure of a 55.5 molal solution of δ is 250 bar

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