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Hex-1-ene reacts with HCI in the absence of peroxide to give 'A' and in the presence of peroxide to give 'B'. What are' A' and' B'?

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A→1-Chlorohexane; B→2-Chlorohexane

A→2-Chlorohexane; B→1-Chlorohexane

A→1-Chlorohexane; B→1-Chlorohexane

A→2-Chlorohexane; B→2-Chlorohexane

answer is D.

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Detailed Solution

There is no effect of peroxide in case of addition of HCI on hex-1-ene. It follows Markovnikov addition to give 2-chlorohexane in both the cases.

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