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Q.

Hexane 1,6 diol on heating with dilute alkali undergoes intra molecular aldol condensation. The final product obtained is

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a

Question Image

b

Question Image

c

Question Image

d

OHC-CH24-CHO

answer is B.

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Detailed Solution

Given, Hexane
When heated with diluted alkali, hexane 1,6 diol experiences intramolecular aldol condensation. The resultant product is

A mixture of hydrocarbons with six carbon atoms known as "hexane" or "hexanes" is used in industry and commerce, and it includes n-hexane, its isomers 2-methylpentane and 3-methylpentane, as well as trace amounts of other hydrocarbons.

The major product will always be the one with a conjugated double bond. This gives the system stability based on resonance. A ring with five members will develop. Only neutralising the acidic mixture will produce a product with a -OH group. If you add too much acid, the final product will have a double bond rather than a -OH group.

Consequently, the right response is B. Question Image

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