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Q.

Hexane 773 K, 10-20 atmCr2O3,  X AlCl3CH3COClY . Y in the above sequence of reaction is

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a

C6H5CH3         

b

C6H5COCH3

c

C6H5CHO         

d

C6H5COOH            

answer is D.

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Detailed Solution

Given data: To find the product Y in the above reaction   

Detailed solution:

Hexane upon heating with Cr2O3C{r_2}{O_3} at 773 K produces benzene

(C6H6{C_6}{H_6}) which is compound X. The obtained benzene reacts with

CH3COClC{H_3}COCl in presence of AlCl3AlC{l_3} produces acetyl benzene

C6H5COCH3{C_6}{H_5}COC{H_3}. Reaction of benzene with CH3COClC{H_3}COCl in presence of

AlCl3AlC{l_3}  is called Friedel crafts acylation.

Hence the correct option is (D)

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