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Q.

ΔH for 3O2(g)2O3(g) is +272 kJ

Then ΔH for Ag2O(s)+O3(g)2Ag(s)+2O2(g) is ΔfH=-32kJ

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a

-104 kJ

b

-168 kJ

c

+168 kJ

answer is C.

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Detailed Solution

For the formation of Ag2O,

2Ag+1/2O2Ag2O  ΔfH=-32 kJ

On multiplying the above reaction by 2 and reversing it, we get,

2Ag2O(s)4Ag(s)+O2(g)ΔH1=+64 kJ3O2(g)2O3(g)ΔH2=+272 kJ

On subtracting above two reactions we get,

2Ag2O(s)+2O3(g)4Ag(s)+4O2(g) ΔH=ΔH1-ΔH2

On dividing the above reaction by 2 , we get

Ag2O(s)+O3(g)2Ag(s)+2O2(g)  ΔH=ΔH1-ΔH22

Thus,

ΔH=64-2722ΔH=-104 kJ

Hence, option (C) is correct.

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