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Q.

HgCl2 and I2 both when dissolved in water containing I- ions, the pair of species formed is

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a

HgI42-, I3-

b

Hg2I2 , I-

c

HgI2, I3-

d

HgI2 , I-

answer is B.

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Detailed Solution

detailed_solution_thumbnail

In a solution containing HgCl2, I2 and I, both HgCl2 and I2 compete for I.
Since formation constant of [Hgl4]2− is 1.9×1030, which is very large,
I will preferentially combine with HgCl2.
HgCl2+2IHgl2+2ClRedppt

Hgl2+2l[Hgl4]2soluble

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