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Q.

HgI2 (solid+2KI (aqK2Hgl4(100yield

If exactly sufficient HgI2 solid is dissolved in an aqueous potassium iodide solution, which of the following may be observed? (all substances are completely ionised)

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a

The elevation in boiling point of water in the solution drops by 25%

b

Freezing point of the solution increased by 25%

c

'ΔTf' of KI solution decreases by 25%

d

Freezing point of the solution decreases by 25%

answer is A, B, C.

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Detailed Solution

HgI2(s)+2KI(aq)K2HgI4
1 mole   2 moles     1 mole
(4 mole particle) (3 mole particle)
4 mole particle changes to 3 moles particles
&   ↓ by 1mole particle so 25% of molarity ↓ 'ΔTf' of KI solution decreases by 25%

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