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Q.

Higher order (>3) reactions are rare due to:

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a

low probability of simultaneous collision of all the reacting species

b

increase in entropy and activation energy as more molecules are involved.

c

shifting of equilibrium towards reactants due to elastic collisions

d

loss of active species on collisions

answer is A.

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Detailed Solution

For higher order (>3) reactions to occur, 3 or more molecules (having energy equal to or greater than activation energy) must simultaneously collide with proper orientation.
The probability for such collisions is very low. Hence these reactions are rare.

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