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Q.

HI was heated in a sealed tube at 4400C till the equilibrium was reached. HIwas found to be 22% decomposed. The equilibrium constant for the dissociation of HI is [2HI H2 + I2]

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a

0.2822

b

0.0796

c

0.0199

d

1.99

answer is C.

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Detailed Solution

Consider the following reaction, 2HI H2 + I2

Now, we know that Initial Concentration of [HI] = 2 moles

            After 22 % dissociation of [HI] = (2*22)/100 = 0.44 moles

Now, 0.44 moles of [HI] will form = 0.44X12 = 0.22 moles of H2 and 0.22 moles of I2.

 KC=[H2][I2][HI]2

 KC=(0.22/V)(0.22/V)(1./56/V)2                               

KC=0.0199

Hence, the correct answer is option (C) 0.0199.

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