Homoleptic octahedral complexes of a metal ion ‘M³⁺’ with three monodentate ligands $L_{1}, L_{2} and L_{3}$ absorb wavelengths in the region of green, blue and red respectively. The increasing order of the ligand strength is

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$L_{3} < L_{2} < L_{1}$

$L_{3} < L_{1} < L_{2}$

$L_{1} < L_{2} < L_{3}$

$L_{2} < L_{1} < L_{3}$

answer is A.

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Detailed Solution

Green Blue Red absorbed wave length:
Order of λ Red>Green>Blue $L_{3} > L_{1} > L_{2}$
Strength of ligand $α Δ α \frac{1}{λ}$
Strength of ligand $L_{2} > L_{1} > L_{3}$

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