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Q.

How do we differentiate between Fe3+ and Cr3+in group III rd ?

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a

By adding excess of NH4OH solution 

b

By decreasing OH- ion concentration

c

By increasing NH4+ ion concentration

d

Both (b) and (c)

answer is A.

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Detailed Solution

Increased NH4+ ions prevent the release of OH- ions, resulting in the solubility of the Fe(OH)3 product. Precipitation varies in color.

Thus, By increasing NH4+ ion concentration and by decreasing OH- ion concentration differentiate between Fe3+ and Cr3+in group III rd.

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