Q.

How does diborane react with
a) H2O b) CO c) NH3 d) N(CH3)3

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Detailed Solution

a) Reacts with H2O : Diborane readily reacts with H2O to give boric Acid.
B2H6+6H2O 2H3BO3(ortho boric acid)+6H2
b) Reacts with CO : Diborane reacts with CO and forms borane carbonyl adduct.
B2H6+2CO2atm1000°C2BH3CO
c) Reacts with NMe3 : Diborane reacts with trimethyl amine and forms an adduct.
B2H6+2NCH33 2BH3NCH33
d) Reacts with NH3 : Diborane reacts with ammonia and forms diammoniate of diborane aduct which further heating gives borazine.
B2H6+2NH3120CB2H62NH3
Diammoniate of diborane
3B2H62NH3200°C2B3N3H6 (Borazole) +12H2

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